Lavery, Christopher B. published the artcilePlatinum-Catalyzed Alkene Cyclohydroamination: Evaluating the Utility of Bidentate P,N/P,P Ligation and Phosphine-Free Catalyst Systems, Safety of 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine, the publication is Organometallics (2010), 29(22), 6125-6128, database is CAplus.
The efficacy of phosphine-free Pt precatalysts including PtCl2 and (COD)PtCl2 in promoting the cyclohydroamination of primary as well as secondary alkyl/arylamines tethered to ¦Á-olefins is demonstrated for the first time. Further catalytic studies examining the use of phenylene-P,N co-ligands, as well as neutral, cationic, and formally zwitterionic complexes derived from the new ligand precursor 1-PPh2-2-P(tBu)2-indene, revealed comparable reactivity in Pt-catalyzed cyclohydroamination catalysis relative to these phosphine-free catalysts.
Organometallics published new progress about 1237588-12-3. 1237588-12-3 belongs to catalysis-chemistry, auxiliary class Mono-phosphine Ligands, name is 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine, and the molecular formula is C30H42NOP, Safety of 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia