Stache, Erin E. published the artcileGeneration of Phosphoranyl Radicals via Photoredox Catalysis Enables Voltage-Independent Activation of Strong C-O Bonds, Formula: C15H24S, the publication is ACS Catalysis (2018), 8(12), 11134-11139, database is CAplus and MEDLINE.
Benzylic alcs. and aryl and alkylcarboxylic acids underwent photochem. deoxygenative reduction via phosphoranyl radicals in the presence of an iridium photoredox catalyst, either Ph3P or Ph2POEt, and an aryl disulfide or thiol to yield methylarenes and aryl and alkyl aldehydes. Carboxylic acids with pendant carbonyl groups or alkenes underwent cyclization reactions via acyl radicals in the presence of the iridium photoredox catalyst, Ph2POEt, and an aryl thiol to yield lactones, a lactam, and cyclic ketones.
ACS Catalysis published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C4H11NO, Formula: C15H24S.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia