Weidlich, Frauke published the artcileMild C-F Activation in Perfluorinated Arenes through Photosensitized Insertion of Isonitriles at 350 nm, Application In Synthesis of 1206-46-8, the publication is Advanced Synthesis & Catalysis (2020), 362(2), 376-383, database is CAplus.
Herein a method for the photochem. activation of aromatic C-F bonds is presented. It is shown that isonitriles RNC (R = 9-oxo-9H-xanthen-2-yl, 1-phenylethan-1-one, 2H-1,3-benzodioxol-5-yl, etc.) selectively insert into aromatic C-F bonds while aliphatic C-F bonds remain unaffected. Mechanistic studies reveal the reaction to proceed via the indirect excitation of the isonitrile to its triplet state by photoexcited acetophenone at 350 nm. Due to the relatively mild light used, the process shows that high functional group tolerance and various compounds of the class of benzimidoyl fluorides (Z)-RN=C(F)R1 (R1 = pentafluorophenyl, tetrafluoropyridin-3-yl, 3-chloro-2,4,5,6-tetrafluorophenyl, etc.) are accessible from aryl isonitriles and com. available perfluorinated arenes such as hexafluorobenzene, Me pentafluorobenzoate, perfluoropyridine, etc.
Advanced Synthesis & Catalysis published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C8H15NO, Application In Synthesis of 1206-46-8.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia