Weinert, Charles S. published the artcileSynthesis, structures and reactivity of novel germanium(II) aryloxide and arylsulfide complexes, Quality Control of 22693-41-0, the publication is Dalton Transactions (2003), 532-539, database is CAplus.
The protonolysis reactions between Ge[N(SiMe3)2]2 and substituted phenols give rise to new germanium(II) aryloxide complexes [Ge(OAr)2]n (n = 2, ArO = OC6H2Me3-2,4,6 (1) or OC6H3iPr2-2,6 (2); n = 1, ArO = OC6H3Ph2-2,6 (3) or OC6HPh4-2,3,5,6 (4)). The solid state structures of 1–3 and 4¡¤3C6H6 were determined by x-ray diffraction and compared to their spectroscopic properties. Compounds 1 and 2 contain bridging aryloxide ligands and the environment about the germanium atoms is pyramidal. Compound 1 reacts with benzil to yield a five-coordinate germanium complex [Ge(OC6H2Me3-2,4,6)(O2C2Ph2)(O2C2HPh2)] (5), while compound 4 reacts with the same reagent to give [Ge(OC6HPh4-2,3,5,6)2(O2C2Ph2)] (6). The x-ray crystal structures of 5¡¤C6H6 and 6¡¤0.5C6H6 also were determined Compound 4 also undergoes an oxidative addition reaction with CH3I to yield the germane [Ge(OC6HPh4-2,3,5,6)2(Me)(I)] (7). A novel arylsulfidegermane, [HGe(SC6H2iPr3-2,4,6)3] (8), was isolated in the reaction between Ge[N(SiMe3)2]2 and HSC6H2iPr3-2,4,6 and was characterized by NMR spectroscopy and an x-ray crystal structure.
Dalton Transactions published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C9H9NO, Quality Control of 22693-41-0.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia