Lindner, Ekkehard published the artcileStudies on steric and electronic effects on the reactivity of diorganyl(trifluoroacetyl)phosphines and their oxides, Related Products of catalysis-chemistry, the publication is Chemische Berichte (1980), 113(8), 2769-78, database is CAplus.
Reactions of phosphines CF3COPRR1 (I; R = Ph, R1 = PhCH2, cyclohexyl, Me3C; R = R1 = m-CF3C6H4, mesityl) with O2 showed that only the mesityl compound is not oxidized. I (R = R1 = m-CF3C6H4, mesityl) react with 30% H2O2 to give, resp., (m-CF3C6H4)2P(O)OH and adduct HP(O)(C6H2Me3-2,4,6)2.1.5H2O2. Oxides CF3COP(O)RR1 (II; R = Ph, R1 = Me3C; R = R1 = mesityl) are hydrolyzed with stoichiometric amounts H2O to give CF3CO2H and HP(O)RR1, whereas II (R = Ph, R1 = PhCH2, cyclohexyl; R = R1 = m-CF3C6H4) react with hydrolytically formed secondary phosphine oxides to give alcs. CF3C[P(O)RR1]2OH (III). III (R = R1 = m-CF3C6H4) is transformed immediately into the phosphinate CF3CH[P(O)RR1][OP(O)RR1]. The preparation of the starting phosphines and their oxides is described and their reactivity related to electronic and steric effects.
Chemische Berichte published new progress about 23897-16-7. 23897-16-7 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Dimesitylphosphine oxide, and the molecular formula is C18H23OP, Related Products of catalysis-chemistry.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia