Delgado, Esther published the artcileIron carbonyls with bulky thiolate ligands: crystal structures of [Fe2(CO)6(¦Ì-SC6H2iPr3-2,4,6)2] and (C6H2iPr3-2,4,6)2S2, Computed Properties of 22693-41-0, the publication is Inorganica Chimica Acta (1999), 284(1), 14-19, database is CAplus.
The reaction of Fe3(CO)12 and bulky thiols HSR (R = C6H2iPr3-2,4,6; C6H2Me3-2,4,6) in toluene yielded [Fe2(CO)6(¦Ì-SR)2] (R = C6H2iPr3-2,4,6 (1), C6H2Me3-2,4,6 (2)). The substitution of one carbonyl by the phosphine Ph2P(CH2)2Si(OEt)3 in complex 1 afforded {Fe2(CO)5[Ph2P(CH2)2Si(OEt)3](¦Ì-SC6H2iPr3-2,4,6)2} (3). Mononuclear [(¦Ç5-C5H5)Fe(CO)2(SC6H2iPr3-2,4,6)] (4) and {(¦Ç5-C5H5)Fe(CO)[Ph2P(CH2)2Si(OEt)3](SC6H2iPr3-2,4,6)} (5) also were obtained. Compound 1 was studied by x-ray diffraction and the structure determined reveals a distorted octahedron geometry around each iron atom and confirms the anti arrangement of aryl substituents in the mol. The preparation of thiol HSC6H2iPr3-2,4,6 yielded the disulfide (C6H2iPr3-2,4,6)2S2 (6) as a byproduct, whose structure was solved by x-ray diffraction. Crystal data: 1, monoclinic, space group P21/a; 6, orthorhombic, space group Pbca.
Inorganica Chimica Acta published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Computed Properties of 22693-41-0.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia