Dilworth, Jonathan R. published the artcileSyntheses and structures of [Re(SC6H3Me2-2,6)3(PPh3)], [Re(SC6H3Me2-2,6)3(ButNC)2], [Re(SC6H2Pri3-2,4,6)3L(PPh3)] (L = N2 or CO) and [ReH4(PPh3)4][ReO(SC6H2Pri3-2,4,6)4], Quality Control of 22693-41-0, the publication is Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1995), 3153-64, database is CAplus.
The hydride [ReH7(PPh3)2] reacted with 2,6-dimethylbenzenethiol in toluene to give [Re(SC6H3Me2-2,6)3(PPh3)] (1). A crystal structure showed a trigonal-bipyramidal geometry about the Re with an agostic interaction to a thiolate Me occupying an apical site, trans to the PPh3 ligand. 1 Reacts rapidly with MeCN to give the known [Re(SC6H3Me2-2,6)3(MeCN)(PPh3)] (2) and with ButNC to form [Re(SC6H3Me2-2,6)3(ButNC)2] (3). The crystal structure of 3 showed trigonal-pyramidal geometry about the Re with asym. coordination of the isocyanide ligands and an unusual configuration for the thiolate aromatic groups. The reactions of the hydrides [ReH7(PPh3)2] and [ReH5(PPh3)3] with 2,4,6-triisopropyl-, 2,6-dimethoxybenzenethiol and tris(2-sulfanylphenyl)phosphine were also studied. With HSC6H2Pri3-2,4,6, [Re(SC6H2Pri3-2,4,6)3(N2)(PPh3)] (4) was formed and its structure determined The preparations and structures of [ReH4(PPh3)4][ReO(SC6H2Pri3-2,4,6)4], [Re{SC6H3(OMe)2-2,6}3(PPh3)] and [Re{P(C6H4S-2)3}(PPh3)] are also discussed. An alternative convenient route to [ReH4(PPh3)4]+ from [ReH5(PPh3)3] is presented.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Quality Control of 22693-41-0.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia