Giguere, Raymond J.’s team published research in Synthetic Communications in 21 | CAS: 4141-48-4

Synthetic Communications published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C15H15OP, Safety of Allyldiphenylphosphine oxide.

Giguere, Raymond J. published the artcileMicrowave heating in synthesis: preparation of allyldiphenylphosphine oxide, Safety of Allyldiphenylphosphine oxide, the publication is Synthetic Communications (1991), 21(21), 2197-201, database is CAplus.

A new one-pot synthesis of allyldiphenylphosphine oxide (I) has been developed using a tandem Sn2′-Michaelis-Arbuzov sequence. The application of microwave heating lowers the reaction time significantly. Thus, reaction of Ph2POEt with CH2:CHCH2Br in a sealed ampul with microwave irradiation for 2 min affords I in 86% yield. Conventional heating of the reactants for 1 h at 130¡ã afford I in 85% yield.

Synthetic Communications published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C15H15OP, Safety of Allyldiphenylphosphine oxide.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia