Schmid, Kyle M. published the artcileA Self-Immolative Spacer That Enables Tunable Controlled Release of Phenols under Neutral Conditions, Product Details of C14H12O3, the publication is Journal of Organic Chemistry (2012), 77(9), 4363-4374, database is CAplus and MEDLINE.
A current challenge in the area of responsive materials is the design of reagents and polymers that provide controlled release of phenols in environments that are less polar than water. In these contexts, a mol. strategy that enables release of nearly any phenol with predictable and tunable rates and without complication from background hydrolysis would substantially increase the precision with which materials can be designed to respond to a particular signal. This Article addresses this problem at the fundamental level by describing the design, synthesis, and phys.-organic characterization of two small mol. self-immolative spacers that are capable of releasing phenols in organic and mixed organic-aqueous solutions The rate of release from these small mol. model systems is predictable and tunable, such that nearly any type of phenol, regardless of pKa value, can be released in neutral solutions without complications from nonspecific background release due to hydrolysis. Furthermore, the release properties of the spacers can be predicted from bond length and conformation data (obtained from crystal structures). On the basis of these results, it should now be possible to incorporate these design elements into materials to enable precise response properties in environments that are not 100% aqueous
Journal of Organic Chemistry published new progress about 31719-76-3. 31719-76-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 4-(Phenoxymethyl)benzoic acid, and the molecular formula is C14H12O3, Product Details of C14H12O3.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia