Taghiof, Majid published the artcileOrganoaluminum and -gallium Thiolates. 1. Synthetic and X-ray Structural Studies, Synthetic Route of 22693-41-0, the publication is Organometallics (1995), 14(6), 2903-17, database is CAplus.
Organoaluminum and -Ga thiolates were prepared in high yield by the reaction of triorganoaluminum and -Ga derivatives with thiols. In this way, [Mes2Al(¦Ì-SBz)]2 (Mes = 2,4,6-Me3C6H2; Bz = CH2Ph) (1), [Me2Al(¦Ì-SSiPh3)]2 (2), [Mes2Al(¦Ì-SPh)]2 (3), {Me2Al[¦Ì-S(2-t-BuC6H4)]}3 (4), {Me2Al[¦Ì-S(2-Me3Si)C6H4]}3 (5), {Me2Al[¦Ì-S(2-i-PrC6H4)]}3 (6), {i-Bu2Al[¦Ì-S(2,4,6-i-Pr3C6H2)]}3 (7), {Me2Al[¦Ì-S(2,6-Me2C6H3)]}4 (8), and {Me2Ga[¦Ì-S(2,6-Me2C6H3)]}4 (9) were prepared and crystallog. characterized. The dimethyl- and dimesitylaluminum thiolates 1–3 are dimeric with four-membered (AlS)2 rings. The structure of 1 was determined in space group P21/n (Number 14): a 10.660(4), b 12.268(2), c 17.793(3) ?, ¦Â 106.94(2)¡ã, Z = 4, R = 6.7%, and Rw = 6.1%. The structures of 2 and 3 were determined in space group P1? (Number 2): a 9.077(2), b 13.847(3), c 16.724(4) ?, ¦Á 101.08(2), ¦Â 95.34(2), ¦Ã 103.38(2)¡ã, Z = 2 (dimers), R = 5.2%, and Rw = 5.1% for 2, and a 11.068(5), b 12.470(3), c 17.654(5) ?, ¦Á 90.97(2), ¦Â 107.77(3), ¦Ã 112.23(3)¡ã, Z = 4, R = 5.9%, and Rw = 4.8% for 3. The dialkylaluminum thiolates, 4–7, are trimeric in the solid state. The structure of 4 was determined in space group P21/c, a 9.324(7), b 18.632(5), c 23.959(9) ?, ¦Â 98.31(5)¡ã, Z = 4 (trimers), R = 7.6%, and Rw = 5.2%; 5 in space group P1?, a 10.149(4), b 14.427(5), c 15.159(4) ?, ¦Á 88.19(3), ¦Â 89.39(3), ¦Ã 88.57(3)¡ã, Z = 2 (trimers), R = 5.0%, and Rw = 5.0%; 6 in space group P1?, a 12.538(5), b 13.180(2), c 13.873(2) ?, ¦Á 74.38(1), ¦Â 64.18(2), ¦Ã 69.44(2)¡ã, Z = 2 (trimers), R = 5.2% and Rw = 4.4%; and 7 in space group P21/c, a 13.935(2), b 22.563(4), c 25.044(4) ?, ¦Â 101.44(1)¡ã, Z = 4 (trimers), R = 12.5%, and Rw = 14.2%. The S atoms in 7 are in a planar environment. Compounds 8 and 9 are tetrameric with eight-membered (MS)4 (M = Al, Ga) ring systems. They are isomorphous, and their structures were determined in space group P1?. For 8 a 8.555(1), b 11.869(1), c 12.688(1) ?, ¦Á 96.546(8), ¦Â 106.34(1), ¦Ã 109.06(1)¡ã, Z = 2, R = 5.0%, and Rw = 5.2%, and for 9 a 8.525(2), b 11.805(3), c 12.714(4) ?, ¦Á 96.36(2), ¦Â 106.46(2), ¦Ã 108.90(2)¡ã, Z = 2, R = 6.1%, and Rw = 6.6%.
Organometallics published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C11H10O, Synthetic Route of 22693-41-0.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia