Coward, Daniel L. published the artcileRadically Initiated Group Transfer Polymerization of Methacrylates by Titanium Amino-Phenolate Complexes, COA of Formula: C16H20N2, the publication is Macromolecules (Washington, DC, United States) (2019), 52(9), 3252-3256, database is CAplus.
Radical initiation of Me methacrylate polymerizations mediated by titanium amino-phenolate complexes gave exceptional control without the need for any cocatalyst or activator. The polymerization proceeds not by a classical controlled radical or coordination insertion mechanism but via a unique bimetallic group transfer process. Detailed exptl. and computational studies support a polymerization mechanism with a titanium(IV)-enolate complex and a second titanium(III) complex that delivers an activated monomer and provides new insight into both titanium-mediated radical reactions and polymerizations
Macromolecules (Washington, DC, United States) published new progress about 140-28-3. 140-28-3 belongs to catalysis-chemistry, auxiliary class Benzenes, name is N1,N2-Dibenzylethane-1,2-diamine, and the molecular formula is C16H20N2, COA of Formula: C16H20N2.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia