Holfter, Hagen published the artcileInsertion of ¦Ã-SO3 into Perfluoroalkyl- and Polyfluoroalkoxysilanes, Recommanded Product: Trimethyl(perfluorophenyl)silane, the publication is Inorganic Chemistry (1994), 33(26), 6369-72, database is CAplus.
The reactions of ¦Ã-SO3 with the silanes RfSi(CH3)3 [Rf = CF3 (1), C6F5 (2), CF2:CF (3), CF2:CFCH2CH2 (8)], and RfSi(n-C3H7)3 [Rf = CF2:CF (7), CF2:CFCH2CH2 (9)] are reported. Several of the expected silyl sulfonates RfSO2OSi(CH3)3 [Rf = CF3 (4), C6F5 (5), CF2:CF (6)] are isolated. The polyfluoroalkenyltin compound CF2:CFCH2CH2Sn(CH3)3 (10) is prepared, and also reacted with ¦Ã-SO3; however, the tin sulfonate does not form. With fluorinated siloxanes RfOSi(CH3)3 [Rf = (CF3)2CH (11), (CF3)2C(CH3) (12), (CF3)2C(C6H5) (13), CF3CH2 (14), (CF3)3C (15), CH2CF2 (16)] reactions with ¦Ã-SO3 give the resp. silyl sulfate esters RfOSO2OSi(CH3)3 in yields up to 85%. The acids CF2:CFSO3H (25) and (HO3SOCH2CF2)2 (26) are easily obtained by the hydrolysis of 6 and 22, resp. The compounds prepared in this study are characterized by 1H, 19F and 29Si NMR, IR and mass spectrometry.
Inorganic Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Recommanded Product: Trimethyl(perfluorophenyl)silane.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia