Ihara, Masataka published the artcileHighly stereocontrolled synthesis of (¡À)-3-oxosilphinene via intramolecular Diels-Alder reaction, Name: Allyldiphenylphosphine oxide, the publication is Journal of the Chemical Society, Chemical Communications (1986), 671-2, database is CAplus.
The triquinane (¡À)-3-oxosilphinene (I), previously isolated from Dugaldia?hoopesii, was prepared in 18 steps from 3-bromo-2-methylcyclopent-2-enone. The key step was the intramol. Diels-Alder reaction of the diene II in o-C6H4Cl2 at 200-220¡ã for 15 h to give 76% tricyclododecene III.
Journal of the Chemical Society, Chemical Communications published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C15H15OP, Name: Allyldiphenylphosphine oxide.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia