Nakamura, Shuichi published the artcile1,4-Asymmetric reduction of ¦Ã-keto sulfoxides bearing the 2,4,6-triisopropylphenyl group, Category: catalysis-chemistry, the publication is Perkin 1 (2000), 3143-3148, database is CAplus.
Reduction of ¦Ã-keto sulfoxides bearing the 2,4,6-triisopropylphenyl group with DIBAL gives ¦Ã-hydroxy sulfoxides with high stereoselectivity in the ratio 95:5. In comparison with the lower stereoselectivities obtained in the reaction of ¦Ã-keto sulfoxides bearing p-tolyl or 2,4,6-trimethylphenyl groups, the sterically bulky (2,4,6-triisopropylphenyl)sulfinyl group is extremely efficient in effecting high 1,4-remote asym. induction.
Perkin 1 published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Category: catalysis-chemistry.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia