Noel-Duchesneau, Ludovik published the artcileMetal-Free Synthesis of 6-Phosphorylated Phenanthridines: Synthetic and Mechanistic Insights, Related Products of catalysis-chemistry, the publication is Organic Letters (2016), 18(22), 5900-5903, database is CAplus and MEDLINE.
A novel and efficient method for the generation of phosphinoyl radicals from the combination of diphenyliodonium salt (Ph2I+,–OTf) with triethylamine (Et3N) in the presence of secondary phosphine oxides is reported. By employing this practical and simple approach, a large variety of 6-phosphorylated phenanthridines have been synthesized through the addition of phosphinoyl radicals to isonitriles as radical acceptors. The reaction works smoothly in the absence of any transition metal or photocatalyst. On the basis of ESR and d. functional theory (DFT) calculations, the mechanism of this reaction is discussed.
Organic Letters published new progress about 23897-16-7. 23897-16-7 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Dimesitylphosphine oxide, and the molecular formula is C18H23OP, Related Products of catalysis-chemistry.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia