Patel, Nimesh R. published the artcileSilylated compounds as transfer reagents with active carbon-chlorine, carbon-fluorine or sulfur-fluorine bonds, Computed Properties of 1206-46-8, the publication is Inorganic Chemistry (1993), 32(22), 4802-6, database is CAplus.
Photolytic insertion of RfCú·N or ClCú·N into the nitrogen-chlorine bond of (CF3)2NCl occurs readily to form (CF3)2NN:C(Rf)Cl [Rf = CF3 (2), C2F5 (3)] or (CF3)2NN:CCl2. Reactions of CF3N(C2F5)N:C(CF3)Cl, 2, or 3 with C6F5SiMe3 in the presence of CsF at 25¡ã result in CF3(Rf)NN:C(Rf‘)C6F5 (Rf, Rf‘ = CF3, C2F5). Analogously, the silylated reagents C6F5SiMe3, Me2NSiMe3, and CF3SiMe3 easily displace chlorine as Me3SiCl from SF5N:C(C2F5)Cl to form SF5N:C(C2F5)X (X = C6F5, NMe2, CF3). The pentafluorophenyl moiety is also readily introduced into (CF3)2NCF2N:C(F)OC(CF3)2CH3 and (CF3)2NN:C(Cl)F by metathesis with C6F5SiMe3 to give (CF3)2NCF2N:C(C6F5)OC(CF3)2CH3 and (CF3)2NN:C(C6F5)N(CF3)2, resp. Under similar mild conditions, CF3N:SF2 forms CF3N:S(Rf)2 [Rf = CF3 (17), C6F5] with CF3SiMe3 and C6F5SiMe3. With ClF, 17 is oxidatively fluorinated to cis and trans-(CF3)2SF4. The nitriles (CF3)2NCN and C2F5CN readily insert into the sulfur-chlorine bond of CF3SCl to give (CF3)2NC(Cl):NSCF3 and C2F5C(Cl):NSF3. With SF5Cl, (CF3)2NCN forms (CF3)2NC(Cl):NSF5.
Inorganic Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Computed Properties of 1206-46-8.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia