Tang, Kaluo published the artcileStudies of trinuclear cadmium cluster complexes. Syntheses and crystal structures of [NMe4][Cd3(SC6H2Pri3-2,4,6)7].C5H12 and [Cd3(SC6H2Pri3-2,4,6)6(HSC6H2Pri3-2,4,6)].CH3OH.7H2O, Application of 2,4,6-Triisopropylbenzenethiol, the publication is Journal of Coordination Chemistry (1994), 31(4), 305-20, database is CAplus.
By the reaction of a sterically hindered arenethiol, 2,4,6-(Me2CH)3C6H2SH (HL), with Cd(NO3)2.4H2O under different conditions, the colorless salt of trinuclear cadmium cluster anion complex [NMe4][Cd3(L)7].C5H12 (I) and the uncharged trinuclear cadmium complex [Cd3(L)6(HL)].MeOH.7H2O (II) were synthesized and structurally characterized. Crystals of I are monoclinic, space group P21/n with a 19.629(6), b 25.608(9), c 25.450(9) ?, ¦Â 107.54(3)¡ã, Z = 4, R = 0.076 for 3839 observed reflections. Crystals of II are triclinic, space group, P1? with a 19.792(10), b 20.508(12), c 33.97(2) ?, ¦Á 85.81(5), ¦Â 86.77(5), ¦Ã 85.12(4)¡ã, Z = 4, R = 0.0921 for 8327 observed reflections. The core of the cluster anion of I is formed by a defect cubane unit with 3 cadmium and 4 sulfur atoms at its vertexes. Each cadmium atom exhibits tetrahedral coordination with 1 terminal sulfur, 2 doubly bridging sulfur and 1 triply bridging sulfur atoms. In complex II, 3 cadmium atoms are coordinated by 6 thiolate (RS–) and 1 thiol (RSH) ligands. Two of 3 cadmium atoms have tetrahedral coordination and 1 is trigonal planar.
Journal of Coordination Chemistry published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C28H29NO4, Application of 2,4,6-Triisopropylbenzenethiol.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia