Cai, Mingli published the artcileMechanism of P-H insertion of ¦Á-imino copper carbenes: 1,1-Insertion or 1,3-insertion?, Recommanded Product: Dimesitylphosphine oxide, the publication is Chemical Physics Letters (2021), 139126, database is CAplus.
The reaction mechanisms of P-H insertion of ¦Á -imino copper carbenes with H-phosphine oxides were theor. investigated by the d. functional theory (DFT). The results revealed that 1,3-insertion was the most preferred pathway due to the strong proton capture ability of the Schiff base, which lowered the energy barrier of P-H insertion. In addition, the effects of substituents on the reactivity of H-phosphine oxides were investigated. For phosphinous acids, the intermol. p-p interaction and ¦Ð-¦Ð packing interaction of phosphine oxide exhibited pos. effects on the reactivity. For diphenylphosphinous acids, the electron-withdrawing substituent resulted in improving the reactivity of diphenylphosphinous acids.
Chemical Physics Letters published new progress about 23897-16-7. 23897-16-7 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Dimesitylphosphine oxide, and the molecular formula is C18H23OP, Recommanded Product: Dimesitylphosphine oxide.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia