Pearson, Anthony J. published the artcileSome Studies on the Uses of 2-Bromoethyl and 2-Iodoethyl Ester Blocking Groups in Peptide Synthesis: Samarium Diiodide-Mediated Deprotection, Computed Properties of 1860-58-8, the publication is Journal of Organic Chemistry (1994), 59(8), 2257-60, database is CAplus.
Deprotection of 2-bromoethyl esters during peptide synthesis is often problematic, owing to competing formation of 2-hydroxyethyl esters. A simple and reproducible method is described for the removal of the 2-bromoethyl group via conversion to the corresponding 2-iodoethyl ester, followed by deprotection of the latter by treatment with samarium diiodide under anhydrous oxygen-free conditions. No racemization was observed for phenylglycine derivatives during the protection/halide exchange/deprotection sequence. Application of this methodol. to a number of peptides as well as simple carboxylate derivatives is described.
Journal of Organic Chemistry published new progress about 1860-58-8. 1860-58-8 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2-(3-(Benzyloxy)phenyl)acetic acid, and the molecular formula is C15H14O3, Computed Properties of 1860-58-8.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia