Pshezhetskii, V. S. published the artcileRole of the cofactor in catalysis on macromolecular models of catalase, Application of N1,N1′-(Ethane-1,2-diyl)bis(ethane-1,2-diamine) dihydrochloride, the publication is Doklady Akademii Nauk SSSR (1972), 204(6), 1492-5 [Biochem], database is CAplus.
The effects of the presence of H2O2 on the form of titration curves of HCl salts of H2NCH2CH2NH2, triethylenetetramine, BuNH2, and Me2NCH2CH2NMe2 were described graphically. Reduction of basicity of the 1st 2 amines was noted in the presence of H2O2 owing to formation of a complex between the reactants. The tertiary amines do not exhibit this behavior and do not form such a complex. The kinetic equations for complex formation were drawn up in general terms and applied to the specific cases above. Catalyzed decomposition of H2O2 over polymeric metal-containing complexes of polyacrylic and polymethacrylic acids in the presence of the 1st 2 amines was discussed. It was concluded that this consists of the interaction of the 2 complexes of H2O2 with the amines with the possibility of forming 2 H bonds between them. The order of such reactions is variable and dependent on pH as this affects the concentration of HO2-, which, along with the H2O2 complexes, undergo catalytic decomposition on the polymeric complexes. Rate constants were reported for decomposition of H2O2 on polymers of the above types in the presence of the 2 active amines and Fe(III).
Doklady Akademii Nauk SSSR published new progress about 38260-01-4. 38260-01-4 belongs to catalysis-chemistry, auxiliary class Chelating Agents, name is N1,N1′-(Ethane-1,2-diyl)bis(ethane-1,2-diamine) dihydrochloride, and the molecular formula is C6H20Cl2N4, Application of N1,N1′-(Ethane-1,2-diyl)bis(ethane-1,2-diamine) dihydrochloride.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia