Wang, Yiheng published the artcileSynthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation, COA of Formula: C18H23OP, the publication is RSC Advances (2018), 8(46), 26271-26276, database is CAplus and MEDLINE.
Reaction of Mes2P(O)Li with (C6F5)2BCl gave access to an oxygen-linked germinal intramol. frustrated Lewis pair Mes2P(O)B(C6F5)2 (1). Compound 1 is stable at room temperature and only decomposes when heated to 90¡ã. NMR anal. and theor. anal. revealed the frustrated nature between the boron and phosphorus centers. Compound 1 shows typical frustrated Lewis pair reactivity when treated with dihydrogen, carbon dioxide, alkyne and alkene. The reaction of 1 with isoprene resulted in selective formation of 3,4-phosphoryl/boryl addition product 8.
RSC Advances published new progress about 23897-16-7. 23897-16-7 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Dimesitylphosphine oxide, and the molecular formula is C19H17N2NaO4S, COA of Formula: C18H23OP.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia