Zemtsov, Artem A. published the artcileReaction of Baylis-Hillman Adducts with Fluorinated Silanes, Application of Trimethyl(perfluorophenyl)silane, the publication is European Journal of Organic Chemistry (2010), 6779-6785, S6779/1-S6779/7, database is CAplus.
Reactions of acylated Baylis-Hillman adducts bearing nitrile, ester, or ketone groups with C6F5-substituted silicon reagents MenSi(C6F5)4-n (n = 1-3) have been studied. The reactions are initiated by Bu4NOAc (5 mol-%) in MeCN or DMF under mild conditions and afford products of allylic substitution of the acetoxy group by the C6F5 carbanion in good yields. Predominant or exclusive formation of one geometrical isomer was observed in all cases (Z for nitriles, E for esters and ketones). For substrates containing carbonyl groups, nucleophilic attack of the C6F5 carbanion chemoselectively occurred at the C=C bond. Reactions of acylated Baylis-Hillman adducts with Me3SiCF3 were found to be inefficient, as the CF3 carbanion had the propensity to attack the C=O bond of substrates with ester or ketone substituents.
European Journal of Organic Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C14H28O5S, Application of Trimethyl(perfluorophenyl)silane.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia