Zhang, Jun-Rong’s team published research in Asian Journal of Organic Chemistry in 6 | CAS: 1772-76-5

Asian Journal of Organic Chemistry published new progress about 1772-76-5. 1772-76-5 belongs to catalysis-chemistry, auxiliary class Benzenes, name is (E)-3-(3-Nitrophenyl)acrylic acid, and the molecular formula is C6H10O7, Product Details of C9H7NO4.

Zhang, Jun-Rong published the artcileDABCO-Promoted Decarboxylative Acylation: Synthesis of ¦Á-Keto and ¦Á,¦Â-Unsaturated Amides or Esters, Product Details of C9H7NO4, the publication is Asian Journal of Organic Chemistry (2017), 6(3), 305-312, database is CAplus.

A metal-free protocol was reported for the synthesis of aryl ¦Á-ketoamides e.g., N,N-dimethyl-2-oxo-2-phenylacetamide and ¦Á,¦Â-unsaturated amides e.g., N,N-dimethylcinnamamide through decarboxylative acylation of various carboxylic acids with carbamic chlorides in good to excellent yields. Further, this method was used for the synthesis of aryl ¦Á-ketoesters e.g., propyl-2-oxo-2-phenylacetate and ¦Á,¦Â-unsaturated esters e.g., Pr cinnamate from corresponding carbonochloridates. 1,4-Diazabicyclo[2.2.2]octane (DABCO) was found to be an effective reagent for decarboxylative acylation of carboxylic acids with carbamic chlorides or carbonochloridates. This protocol offered several advantages such as metal-free and mild conditions, simple operation, a broad substrate scope and high yields.

Asian Journal of Organic Chemistry published new progress about 1772-76-5. 1772-76-5 belongs to catalysis-chemistry, auxiliary class Benzenes, name is (E)-3-(3-Nitrophenyl)acrylic acid, and the molecular formula is C6H10O7, Product Details of C9H7NO4.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia