Guilleme, Julia published the artcileDirect Access to Axially Substituted Subphthalocyanines from Trimethylsilyl-Protected Nucleophiles, Related Products of catalysis-chemistry, the publication is Organic Letters (2015), 17(19), 4722-4725, database is CAplus and MEDLINE.
A new synthetic one-step approach to perform the axial ligand exchange reaction in subphthalocyanines that employs trimethylsilyl-protected nucleophiles as starting materials is reported. Theor. calculations indicate that the exchange reaction proceeds through a similar 4-centered ¦Ò-bond metathesis transition state as the substitution with phenols. This direct method allowed us to synthesize new axial derivatives of singular importance within the chem. of subphthalocyanines, for which the reactivity and x-ray crystalline structure were studied.
Organic Letters published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Related Products of catalysis-chemistry.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia