Li, Yuanming’s team published research in Journal of Organic Chemistry in 78 | CAS: 2909-77-5

Journal of Organic Chemistry published new progress about 2909-77-5. 2909-77-5 belongs to catalysis-chemistry, auxiliary class Amine,Benzene, name is 2,6-Diisopropyl-N,N-dimethylaniline, and the molecular formula is C14H23N, Category: catalysis-chemistry.

Li, Yuanming published the artcileAmide Bond Formation through Iron-Catalyzed Oxidative Amidation of Tertiary Amines with Anhydrides, Category: catalysis-chemistry, the publication is Journal of Organic Chemistry (2013), 78(11), 5638-5646, database is CAplus and MEDLINE.

A general and efficient method for amide bond synthesis has been developed. The method allows for synthesis of tertiary amides from readily available tertiary amines and anhydrides in the presence of FeCl2 as catalyst and tert-Bu hydroperoxide in water (T-Hydro) as oxidant. Mechanistic studies indicated that the in situ-generated ¦Á-amino peroxide of tertiary amine and iminium ion act as key intermediates in this oxidative transformation.

Journal of Organic Chemistry published new progress about 2909-77-5. 2909-77-5 belongs to catalysis-chemistry, auxiliary class Amine,Benzene, name is 2,6-Diisopropyl-N,N-dimethylaniline, and the molecular formula is C14H23N, Category: catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia