Moons, Sam J. published the artcile¦Á-Selective Glycosylation with ¦Â-Glycosyl Sulfonium Ions Prepared via Intramolecular Alkylation, Recommanded Product: 2,4,6-Trimethoxybenzenethiol, the publication is Journal of Organic Chemistry (2019), 84(7), 4486-4500, database is CAplus and MEDLINE.
Stereoselective glycosylation remains the main challenge in the chem. synthesis of oligosaccharides. Herein we report a simple method to convert thioglycosides into ¦Â-sulfonium ions via an intramol. alkylation reaction leading to highly selective glycosylation for a variety of glycosyl acceptors. The influence of the thioglycoside substituent and the protecting group pattern on the glycosyl donor was investigated and showed a clear correlation with the observed stereoselectivity.
Journal of Organic Chemistry published new progress about 77189-99-2. 77189-99-2 belongs to catalysis-chemistry, auxiliary class Thiophenol,Benzene,Ether, name is 2,4,6-Trimethoxybenzenethiol, and the molecular formula is C9H12O3S, Recommanded Product: 2,4,6-Trimethoxybenzenethiol.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia