Wang, Qiang published the artcileFormation of nickel-thiolate aggregates via reaction with CH2Cl2, Synthetic Route of 22693-41-0, the publication is Chemical Communications (Cambridge, United Kingdom) (2003), 2776-2777, database is CAplus and MEDLINE.
Reaction of newly prepared Ni-dithiolate complex [Ni(L1)(dppe)] with CH2Cl2 affords the novel pentanuclear complex [Ni5Cl2(L1)4(dppe)2] (1) (H2L1 = 1,2-mercaptomethyl-3,4-dimethylbenzene), while [Ni(L1)(dcpe)] (dcpe = 1,2-bis(cyclohexylphosphino)ethane) reacts with CH2Cl2 to give binuclear [Ni2Cl2(L2)(dcpe)2] (2) in which two L1 units are linked through a sulfur by a methylene group derived from CH2Cl2 to form L2 (H2L = I). 1 And 2 are characterized by crystal structure anal. When [NiCl2(PP)] (PP = dppe, dcpe) is reacted with 2,4,6-triisopropylthiophenol (HL3) or 2-mercaptomethylbenzenethiol (H2L4) n the presence of NaOMe in MeOH, the corresponding mononuclear Ni thiolate complexes [Ni(L3)2(PP)] and [Ni(L3)(PP)] were obtained.
Chemical Communications (Cambridge, United Kingdom) published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C11H8N2O2, Synthetic Route of 22693-41-0.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia