Wolfgramm, Regine’s team published research in Organometallics in 17 | CAS: 312-40-3

Organometallics published new progress about 312-40-3. 312-40-3 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Difluorodiphenylsilane, and the molecular formula is C14H12O3, Application of Difluorodiphenylsilane.

Wolfgramm, Regine published the artcileIrreversible Rearrangement of Silyl Groups between Oxygen and Nitrogen in Tris(silyl)hydroxylamines, Application of Difluorodiphenylsilane, the publication is Organometallics (1998), 17(15), 3222-3226, database is CAplus.

Diorganofluorosilylation of 1,2-bis(trimethylsilyl)hydroxylamines at low temperatures gives exclusively O-(diorganofluorosilyl)-N,N-bis(trimethylsilyl)hydroxylamines 1. The thermal rearrangement of 1 to the isomeric N-(diorganofluorosilyl)-N,O-bis(trimethylsilyl)hydroxylamines 2 is irreversible, and the exptl. data suggest an intramol. course of the isomerization. Ab initio and d. functional calculations for model compounds demonstrate the dyotropic course of the rearrangement. Anomeric stabilization of 2 by more favorable neg. F-Si-N and O-Si-C hyperconjugation is important for the irreversibility of the reaction.

Organometallics published new progress about 312-40-3. 312-40-3 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Difluorodiphenylsilane, and the molecular formula is C14H12O3, Application of Difluorodiphenylsilane.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia