Burger, Klaus published the artcileHexafluoroacetone as protective group and activating reagent in amino acid and peptide chemistry. 10. Synthesis of 3-(thiazol-4-yl)alanine and 3-(selenazol-4-yl)alanine derivatives from aspartic acid, Computed Properties of 6972-05-0, the publication is Synthesis (1992), 1145-50, database is CAplus.
3-(Thiazol-4-yl)alanines I (R = Ph, 4-MeC6H4, 4-MeOC6H4, 2-furyl, NMe2, 4-FC6H4, 2-thienyl, H, Me; R1 = H, Me) and the 3-(selenazol-4-yl)alanine II were obtained from aspartic acid via 2,2-bis(trifluoromethyl)-4-(3-bromo-2-oxopropyl)-1,3-oxazolidin-5-one in a Hantzsch synthesis, using hexafluoroacetone as protective group.
Synthesis published new progress about 6972-05-0. 6972-05-0 belongs to catalysis-chemistry, auxiliary class Thiourea,Amine,Aliphatic hydrocarbon chain,Amide, name is 1,1-Dimethylthiourea, and the molecular formula is C3H8N2S, Computed Properties of 6972-05-0.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia