Iwasaki, Takanori’s team published research in Organic Letters in 18 | CAS: 1206-46-8

Organic Letters published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Product Details of C9H9F5Si.

Iwasaki, Takanori published the artcileMulticomponent Coupling Reaction of Perfluoroarenes with 1,3-Butadiene and Aryl Grignard Reagents Promoted by an Anionic Ni(II) Complex, Product Details of C9H9F5Si, the publication is Organic Letters (2016), 18(19), 4868-4871, database is CAplus and MEDLINE.

In the presence of in situ-generated anionic nickel catalysts, aryl Grignard reagents such as 4-fluorophenylmagnesium bromide, 1,3-butadiene, and perfluoroarenes such as perfluorobenzene underwent diastereoselective and chemoselective three-component coupling reactions to yield (aryl)(perfluoroaryl)octadienes such as I. A thermally unstable anionic nickel complex II?Li(12-crown-4)2+ was prepared from PhLi, 1,3-butadiene, Ni(cod)2, and 12-crown-4 and its crystal structure determined and used as a catalyst for the three-component coupling reaction.

Organic Letters published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Product Details of C9H9F5Si.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia