Kumar, Amit published the artcileSilicon Fluorides for Acid-Base Catalysis in Glycosidations, Application In Synthesis of 312-40-3, the publication is Advanced Synthesis & Catalysis (2012), 354(8), 1489-1499, database is CAplus.
Adduct formation between alcs. as glycosyl acceptors and phenylsilicon trifluoride (PhSiF3) as catalyst permits acid-base-catalyzed glycosidations with O-glycosyl trichloroacetimidates as glycosyl donors. In this way, from various glycosyl donors and acceptors 1,2-trans- and some 1,2-cis-glycosides could be obtained with high anomeric selectivity. A preference for an intramol. bimol. nucleophilic substitution (SN2-type) reaction course with concomitant donor and acceptor activation is supported by the results.
Advanced Synthesis & Catalysis published new progress about 312-40-3. 312-40-3 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Difluorodiphenylsilane, and the molecular formula is C12H10F2Si, Application In Synthesis of 312-40-3.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia