Molaei, Somayeh’s team published research in Microporous and Mesoporous Materials in 319 | CAS: 119-80-2

Microporous and Mesoporous Materials published new progress about 119-80-2. 119-80-2 belongs to catalysis-chemistry, auxiliary class sulfides,Carboxylic acid,Benzene, name is 2,2′-Dithiodibenzoic acid, and the molecular formula is C14H10O4S2, Product Details of C14H10O4S2.

Molaei, Somayeh published the artcileA green methodology for thioether formation reaction and synthesis of symmetrical disulfides over new heterogeneous Cu attached to bifunctionalized mesoporous MCM-41, Product Details of C14H10O4S2, the publication is Microporous and Mesoporous Materials (2021), 110990, database is CAplus.

New recyclable Cu attached bifunctionalized mesoporous MCM-41 (MCM-41-quinoline-2-4-dicarboxylic acid-Cu) has been developed through post-functionalization modification of silica MCM-41. Novel catalyst was effective, and greener catalyst for the thioether formation reaction between aryl halides and S8, instead of thiol, and synthesis of disulfides by coupling of aromatic thiols with mol. O2(air). The protocol was a greener way toward the thioether formation reaction and the synthesis of disulfides and shows a 100% atom economy. Herein, thioether was produced as the only product. One way that chemists evaluate a synthetic route was to focus on its atom economy, the proportion of reactant atoms that end up in the desired product. The efficiency of synthesis was quantified in terms of the percent atom economy, the catalytic system exhibits high chemo-selectivity, as shown by high yields. The catalyst can be easily separated using simple recovery and reused several times with consistent activity.

Microporous and Mesoporous Materials published new progress about 119-80-2. 119-80-2 belongs to catalysis-chemistry, auxiliary class sulfides,Carboxylic acid,Benzene, name is 2,2′-Dithiodibenzoic acid, and the molecular formula is C14H10O4S2, Product Details of C14H10O4S2.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia