Morrelli, Derek published the artcileRole of solvent dielectric constant on the enthalpy-entropy compensation in the hindered amide bond rotation, Product Details of C8H8O2, the publication is Chemical Physics Letters (2022), 139412, database is CAplus.
Dynamic NMR (DNMR) experiments are performed on a series of analogs derived from N, N-diethyl-m-toluamide (DEET) in six different solvents of varying dielec. constant from toluene-d8 (¦Å = 2.38) to DMSO-d6 (¦Å = 46.7). The thermodn. parameters of the restricted rotation to the solvent dielec. constant do not have a straightforward correlation relationship between them. However, the activation enthalpy and entropy of more than sixty different exptl. measurements indicate that enthalpy-entropy compensation (EEC) was independent of the solvent condition with a compensation temperature of 287.81 ¡À 3.95 K. The results, therefore, support the broader role of EEC on the partial amide bond dynamics in the DEET analogs over the temperature range studied.
Chemical Physics Letters published new progress about 118-90-1. 118-90-1 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Natural product, name is 2-Methylbenzoic acid, and the molecular formula is C8H8O2, Product Details of C8H8O2.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia