Safar, M.’s team published research in Collection of Czechoslovak Chemical Communications in 40 | CAS: 14707-75-6

Collection of Czechoslovak Chemical Communications published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Synthetic Route of 14707-75-6.

Safar, M. published the artcileNitrogen compounds of adamantane. VIII. Chromatographic separation of azaadamantanes and their derivatives in a gas liquid system, Synthetic Route of 14707-75-6, the publication is Collection of Czechoslovak Chemical Communications (1975), 40(11), 3334-8, database is CAplus.

Gas chromatog. separation of 1-azaadamantane (I), 1,3-diazaadamantane (II), 1,3,5-triazaadamantane (III), 1,3,5,7-tetraazaadamantane (IV), and their derivatives was investigated. Elution data for I, II, III, IV, 7-substituted-1,3,5-triazaadamantanes (substituents = Cl, Br, NO2, NH2, MeNH, Me2N), adamantane, 1-bromo- and 1-aminoadamantane, and eicosane, rel. elution volumes of 7-amino-1,3,5-triazaadamantane aldimines, and homomorphic factors for I, II, III, and IV were determined A flame ionization detector and N carrier gas at 50 ml/min were used. Stainless steel columns (6 mm ¡Á 1.2 m) packed with 3 types of fillings were used: type A:12.3 g Chromaton N-AW-DMCS (particle size 0.16-0.20 mm) containing 5% (weight) SE-30 at 125 and 220¡ã, type B: 10.9 g Chromaton N-AW-HMDS (particle size 0.16-0.20 mm) with 10% (weight) OS-124 (Lachema, Brno) at 190¡ã; and type C: 9.7 g Chromaton N (particle size 0.20-0.25 mm) with 5% (weight) polyethylene glycol (mol. weight 1500) and 1% KOH at 160¡ã. Chromatog. behavior of the substances with respect to their structure and interaction with the stationary phase is discussed.

Collection of Czechoslovak Chemical Communications published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Synthetic Route of 14707-75-6.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia