Yu, Mingming published the artcileElectrochemical-induced benzyl C-H amination towards the synthesis of isoindolinones via aroyloxy radical-mediated C-H activation, Recommanded Product: 2-Methylbenzoic acid, the publication is Green Chemistry (2022), 24(4), 1445-1450, database is CAplus.
A novel electrochem. strategy to selectively and sustainably access isoindolinones I [R1 = H, 7-Me, 5-F, etc.; R2 = H, Me, Et, n-Pr, i-Pr, n-Bu; R3 = Me, n-Pr, i-Pr, n-Bu, cyclopropyl, CD3] using simple o-alkyl benzoic acids and nitriles as substrates under metal catalyst and external oxidant-free conditions was developed. Meanwhile, nitrile as the nitrogen source plays a vital role, as its derived intermediate facilitates the construction of the amide bond in the product. Mechanistic investigations suggest that aroyloxy radicals were involved in this transformation, which initiated the benzylic C-H amination event by a 1,5-HAT process. The protocol showed a very good functional group tolerance.
Green Chemistry published new progress about 118-90-1. 118-90-1 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Natural product, name is 2-Methylbenzoic acid, and the molecular formula is C20H28B2O4S2, Recommanded Product: 2-Methylbenzoic acid.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia