Klingebiel, Uwe’s team published research in Journal of Organometallic Chemistry in 179 | CAS: 312-40-3

Journal of Organometallic Chemistry published new progress about 312-40-3. 312-40-3 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Difluorodiphenylsilane, and the molecular formula is C12H10F2Si, Recommanded Product: Difluorodiphenylsilane.

Klingebiel, Uwe published the artcileFluorosilyl-substituted N,N- and N,O-bis(trimethylsilyl)hydroxylamines, Recommanded Product: Difluorodiphenylsilane, the publication is Journal of Organometallic Chemistry (1979), 179(4), 391-6, database is CAplus.

Fluoro- and aminofluorosilanes react with the Li salt on N,O-bis(trimethylsilyl)hydroxylamine with LiF elimination and substitution. Alkyl- and aminofluorosilanes give O-fluorosilyl-N,N-bis(trimethylsilyl)hydroxylamines, arylfluorosilanes give N-fluorosilyl-N,O-bis(trimethylsilyl)hydroxylamines. By the further reaction of O-difluorosilyl-N,N-bis(trimethylsilyl)hydroxylamine with the lithiated hydroxylamine, O,O‘-fluoromethylsilyldi[N,N-bis(trimethylsilyl)hydroxyalmine] is formed. On heating N-difluorophenylsilyl-N,O-bis(trimethylsilyl)hydroxylamine, di[fluorophenylsilyl(methyl)amino]pentamethylsiloxane is formed by Me group migration.

Journal of Organometallic Chemistry published new progress about 312-40-3. 312-40-3 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Difluorodiphenylsilane, and the molecular formula is C12H10F2Si, Recommanded Product: Difluorodiphenylsilane.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia