Kremer, Silke published the artcileSilver Compounds in Synthetic Chemistry. Part 8. Complexes of Perfluoroorgano Silver(I) Derivatives with 4-Dimethyl-aminopyridine (DMAP), Recommanded Product: Trimethyl(perfluorophenyl)silane, the publication is Zeitschrift fuer Anorganische und Allgemeine Chemie (2014), 640(12-13), 2458-2462, database is CAplus.
Attempted syntheses of AgRf¡¤DMAP were performed using the established route starting from AgF and Me3SiRf (Rf = CF3, C2F5, C6F5) followed by the addition of DMAP. Unexpectedly, reactions with perfluoroalkylsilver(I) derivatives yielded products, which underwent known equilibrium, while exclusively the pentafluorophenyl derivative exhibits its zwitterionic nature in solution and in the solid state. Moreover, both perfluoroalkyl derivatives investigated decomposed slowly but more or less selectively even at -20¡ã in solution: AgC2F5¡¤DMAP mainly into AgOCOCF3 (probably under the influence of moisture) and AgCF3¡¤DMAP mainly into the unprecedented derivative 3-trifluoromethyl-4-dimethylaminopyridine. The mol. structure of AgC6F5¡¤DMAP was elucidated showing a twist arrangement of the aromatic rings quite unusual for linear coordinated species.
Zeitschrift fuer Anorganische und Allgemeine Chemie published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Recommanded Product: Trimethyl(perfluorophenyl)silane.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia