Tejo, Ciputra’s team published research in Chemical Communications (Cambridge, United Kingdom) in 54 | CAS: 4141-48-4

Chemical Communications (Cambridge, United Kingdom) published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C17H19N3O6, COA of Formula: C15H15OP.

Tejo, Ciputra published the artcileDearylation of arylphosphine oxides using a sodium hydride-iodide composite, COA of Formula: C15H15OP, the publication is Chemical Communications (Cambridge, United Kingdom) (2018), 54(14), 1782-1785, database is CAplus and MEDLINE.

A new protocol for the dearylation of arylphosphine oxides was developed using sodium hydride (NaH) in the presence of lithium iodide (LiI). Reaction of triarylphosphine oxides Ar2PPh with NaH/LiI afforded sodium phosphinites Ar2PONa, which were trapped with alkyl halides RX to give diarylalkylphosphine oxides Ar2P(O)R in good to excellent yields. The transient sodium phosphinite could be functionalized with a range of electrophiles in a one-pot fashion.

Chemical Communications (Cambridge, United Kingdom) published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C17H19N3O6, COA of Formula: C15H15OP.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia