Toyota, Masahiro published the artcileSynthesis of a cancer growth-inhibiting diterpene – stereoselective formal synthesis of (+)-aphidicolin, Product Details of C15H15OP, the publication is Tetrahedron (1996), 52(31), 10347-10362, database is CAplus.
Stereoselective formal synthesis of the diterpene tetraol (+)-aphidicolin is described, employing as key steps the cycloisomerization of the enyne I to provide the bicyclo[3.2.1]octane derivative II and the intramol. Diels-Alder reaction of the triene III to form the aphidicolane-type ring system. This route is, in principal, highly stereocontrolled and extremely efficient.
Tetrahedron published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C9H12BNO4, Product Details of C15H15OP.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia