Tyrra, Wieland’s team published research in Journal of Fluorine Chemistry in 126 | CAS: 1206-46-8

Journal of Fluorine Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C15H14O3, Application of Trimethyl(perfluorophenyl)silane.

Tyrra, Wieland published the artcileOn the attempted synthesis of salts with the trimethyl[bis(pentafluorophenyl)]silicate ion, [Me3Si(C6F5)2]–-A polyphenyl problem, Application of Trimethyl(perfluorophenyl)silane, the publication is Journal of Fluorine Chemistry (2005), 126(9-10), 1303-1306, database is CAplus.

Reactions of Me3SiC6F5 and MF (M = Cs, [NMe4]) in molar ratios varying from 1:1 to 2:1 in a temperature range between -70 ¡ãC and ambient proceed more or less selectively to form 1-H-perfluoro-4,4′-polyphenyls, 1-H(C6F4)nF, independent of the solvent used (DME, THF). The silicates expected, M[Me3Si(C6F5)F] and M[Me3Si(C6F5)2], were not detected even in low temperature NMR experiments The polymeric material formed was identified after aqueous working up as a mixture of 1-H(C6F4)nF (n = 4-13) by elemental analyses and EI mass spectrometric studies.

Journal of Fluorine Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C15H14O3, Application of Trimethyl(perfluorophenyl)silane.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia