Legnani, Luca published the artcileDirect and Practical Synthesis of Primary Anilines through Iron-Catalyzed C-H Bond Amination, Product Details of C6H12F3NO5S, the publication is ACS Catalysis (2016), 6(12), 8162-8165, database is CAplus.
The direct C-H amination of arenes is an important strategy to streamline the discovery and preparation of functional mols. Herein, we report an operationally simple arene C-H amination reaction that, in contrast to most literature precedence, affords directly the synthetically versatile primary aniline products without relying on protecting group manipulations. Inexpensive Fe(II) sulfate serves as a convenient catalyst for the transformation. The reaction tolerates a wide scope of arenes, including structurally complex drugs. Importantly, the arene substrates are used as limiting reagents in the transformation. This operationally simple transformation should considerably accelerate the discovery of medicines and functional mols.
ACS Catalysis published new progress about 1293990-73-4. 1293990-73-4 belongs to catalysis-chemistry, auxiliary class Aliphatic Chain, name is O-Pivaloylhydroxylamine trifluoromethanesulfonate, and the molecular formula is C6H12F3NO5S, Product Details of C6H12F3NO5S.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia