Liu, Rong Qiang published the artcile2-Alkenyldiphenylphosphine oxides and PO-ylides derived thereof in trans selective Horner-Wittig olefination reactions, COA of Formula: C15H15OP, the publication is Synlett (1996), 1195-1196, database is CAplus.
Allylic PO-ylides generated by deprotonation of 2-alkenyldiphenylphosphine oxides with BuLi were used to prepare 1,3-dienes trans-selectively. The (Z/E) ratios of the newly formed double bond are 1:99 when straight-chain, while they were 2:98 to 4:96 when ¦Â-branched aliphatic, and 4:96 to 6:94 when aromatic aldehydes were employed.
Synlett published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C15H15OP, COA of Formula: C15H15OP.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia