Onuska, Nicholas P. R.’s team published research in Synlett in 31 | CAS: 22693-41-0

Synlett published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Synthetic Route of 22693-41-0.

Onuska, Nicholas P. R. published the artcileAnti-Markovnikov Hydroazidation of Activated Olefins via Organic Photoredox Catalysis, Synthetic Route of 22693-41-0, the publication is Synlett (2020), 31(1), 55-59, database is CAplus and MEDLINE.

Herein was disclosed a method for the anti-Markovnikov hydroazidation of activated olefins, catalyzed by an organic acridinium salt under irradiation from blue LEDs to afford (azidoalkyl)arenes such as ArCH(R)CH(R1)N3 [R = H, Me, Ph; R1 = H, Me, CH2OTBS, etc.; Ar = Ph, 2-thienyl, 2-naphthyl, etc.]. This method was applicable to a variety of substituted and terminal styrenes and several vinyl ethers, yielding synthetically versatile hydroazidation products in moderate to excellent yield.

Synlett published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Synthetic Route of 22693-41-0.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia