Talotta, Carmen published the artcileSynthesis and supramolecular features of hybrid POM/onium solid-state assemblies, COA of Formula: C16H20N2, the publication is Supramolecular Chemistry (2016), 28(5-6), 403-417, database is CAplus.
Polyoxomolybdate-based organic-inorganic hybrid architectures were synthesized and characterized by x-ray crystallog. The supramol. assemblies present rows of metallic clusters H-bonded by ammonium cations, with a 1:2 molybdate/ammonium ratio. The organic moieties of the ammonium cations establish hydrophobic contact among them such as van der Waals, C-H¡¤¡¤¡¤¦Ð and ¦Ð¡¤¡¤¡¤¦Ð interactions that stabilize the supramol. architectures. In particular, for compound (5) the n-alkyl tails pack closely together giving a lipid-like bilayer. In compound (6), the aromatic Ph rings of the organic cation allow the stabilization of the supramol. architecture by C-H¡¤¡¤¡¤¦Ð and ¦Ð¡¤¡¤¡¤¦Ð interactions. Regarding the x-ray structure of the compound (11), the tetraanionic octa-molybdate [Mo8O26]4- cluster is surrounded by four Et-triphenyl-phosphonium cations. Running along the b-axis open channels are occupied by DMF solvent mols. A soaking experiment in n-pentane with the corresponding crystals of compound 11 afforded a crystal structure very different from the native one.
Supramolecular Chemistry published new progress about 140-28-3. 140-28-3 belongs to catalysis-chemistry, auxiliary class Benzenes, name is N1,N2-Dibenzylethane-1,2-diamine, and the molecular formula is C5H6BNO2, COA of Formula: C16H20N2.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia