Tong, Yu Ying published the artcileSyntheses and properties of the gold(I) complexes with bulky thiolates [Au(SR)]6 and [Au(SR)(PPh3)] (R = C6H2Me3-2,4,6 or C6H2Pr3i-2,4,6), and the molecular structure of [Au(SC6H2Pr3i-2,4,6)(PPh3)], Formula: C15H24S, the publication is Transition Metal Chemistry (London) (1995), 20(4), 372-5, database is CAplus.
[Au(SR)]6 (R = C6H2Me3-2,4,6 or C6H2Pri3-2,4,6) prepared by treatment of chloroauric acid in water with thiodiglycol followed by reaction with the appropriate thiol (HSR) in CHCl3, can add PPh3 in CH2Cl2 to give [Au(SR)(PPh3)], which, alternatively, can be obtained from reaction of [AuCl(PPh3)] in THF with HSR in the presence of KOH-EtOH. The mol. structure of [Au(SC6H2Pri3-2,4,6)(PPh3)] was determined by x-ray diffraction anal.
Transition Metal Chemistry (London) published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C10H12F6N4O6PdS2, Formula: C15H24S.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia