Bochmann, Manfred published the artcileChalcogenolato complexes of bismuth and antimony. Syntheses, thermolysis reactions, and crystal structure of Sb(SC6H2Pri3-2,4,6)3, Category: catalysis-chemistry, the publication is Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1995), 1649-52, database is CAplus.
Sb(III) and Bi(III) complexes of sterically demanding arenechalcogenolato ligands, M(EC6H2R’3-2,4,6)3 (E = S or Se; M = Sb or Bi; R’ = Me, Pri or But) were prepared by either protolysis of the amides M[N(SiMe3)2]3 with arenechalcogenols, or from MCl3 by halide exchange (M = Bi or Sb). The complexes are monomeric in the solid state and sublime readily. The crystal structure of Sb(SC6H2Pri3-2,4,6)3 was determined by x-ray diffraction. The compound possesses a trigonal-pyramidal geometry, with Sb-S distances of 2.418(2)-2.438(2) ? and S-Sb-S angles of 94.69(7)-98.29(8)¡ã. Preliminary x-ray results on Bi(SeC6H2Pri3-2,4,6)3 showed that the compounds of Sb and Bi are isostructural. Thermolytic decomposition of some of the compounds was carried out in the solid state. Compounds with R’ = Me or Pri undergo reductive elimination to give elemental Bi or Sb, whereas the bulky selenolates M(SeC6H2But3-2,4,6)3 afford M2Se3.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Category: catalysis-chemistry.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia