Gamage, Swarna A.’s team published research in Australian Journal of Chemistry in 43 | CAS: 22693-41-0

Australian Journal of Chemistry published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Related Products of catalysis-chemistry.

Gamage, Swarna A. published the artcileIntramolecular aromatic substitution with bisthiocarbocations. Variations of Lewis acid, solvent and orthothio substituents, Related Products of catalysis-chemistry, the publication is Australian Journal of Chemistry (1990), 43(5), 815-24, database is CAplus.

The effects of Lewis acid, solvent and orthothio substituent have been examined with regard to intramol. electrophilic aromatic substitution with bisthiocarbocations. A suspension of silver trifluoromethanesulfonate in dichloromethane, creating bis(arylthio)carbocations, was found to be the most effective for annulation of six-membered rings. E.g., o-phenylene trithiocarbonate was condensed with 3-MeOC6H4(CH2)3I to give 2-[3-(3-methoxyphenyl)propyl]-2-methylthio-1,3-benzodithiole which was subject to intramol. aromatic substitution to give 6-methoxy-1-tetralone.

Australian Journal of Chemistry published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Related Products of catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia