Nasreddine, M. published the artcileNew and effective route to N-(2-F-alkyl ethyl) ¦Á-amino acids, Application of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, the publication is Synthetic Communications (1992), 22(11), 1547-54, database is CAplus.
A new and effective procedure is described for the synthesis of the title ¦Á-amino acids F3C(CF2)nCH2CH2NHCHRCO2H (I; n = 5, 7, R = H, Me, Et, Pr, Bu) which involves a solid-liquid phase transfer catalysis method. Thus, substitution of bromoalkanoates BrCHRCO2Et with amines F3C(CF2)nCH2CH2NH2 in MeCN in the presence of K2CO3 and PhCH2N+Et3 Cl– gave 76-96% of the corresponding amino esters, which were saponified to give 71-97% I.
Synthetic Communications published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Application of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia