Nicolaou, K. C. published the artcileIodine(V) Reagents in Organic Synthesis. Part 2. Access to Complex Molecular Architectures via Dess-Martin Periodinane-Generated o-Imidoquinones, Application of Allyldiphenylphosphine oxide, the publication is Journal of the American Chemical Society (2002), 124(10), 2221-2232, database is CAplus and MEDLINE.
2-Amido-1,4-benzoquinones can be prepared from 4-substituted anilides lacking pendant alkenes by treatment with DMP and water followed by careful workup under neutral conditions. The oxidative preparation of 2-amido-1,4-benzoquinones has been used in the synthesis of the natural products epoxyquinomycin B and BE-10988 and in the preparation of a macrocyclic amide with a tetrahydronaphthoquinone moiety. Ortho-substituted N-aryl acetamides lacking pendant alkenes undergo oxidation with DMP and water to give o-imidoquinones which are stable for several months when stored under argon at low temperature in the absence of light. O-imidoquinones undergo intermol. Diels-Alder cycloadditions with vinyl ethers and sulfides to give phenoxazines. The treatment of anilides containing pendant alkenes with Dess-Martin periodinane (DMP) in the presence of water gives oxazine-containing polycyclic compounds by stereoselective oxidation to o-imidoquinones followed by stereoselective intramol. Diels-Alder cycloaddition The isobutyrylaminophenylheptadiene (E)-Me2CHCONH-4-C6H4CH2CH2CH2CH:CHCH:CH2 undergoes stereoselective oxidative cyclization upon treatment with DMP in methylene chloride to give ketoamidohydroxyphenalenone I in 28% yield and an amidoquinone which undergoes thermal Diels-Alder cyclization to give hexahydrobenzindene II in 25% yield; I and II are related to the natural products pseudopterosin A and elisabethin A, resp. The ketohydroxyamide moiety in I undergoes cyclization, condensation, and cyclocondensation reactions with aromatic amines, aromatic diamines, amino acid esters, and amino alcs. to give spirocycles, fused diazaheterocycles, and phenalene derivatives
Journal of the American Chemical Society published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C15H15OP, Application of Allyldiphenylphosphine oxide.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia