Piela, Katarzyna published the artcileElectrical Anharmonicity and Vibronic Couplings Contributions to Optical Nonlinearity of N-Benzyl-2-methyl-4-nitroaniline Crystal Studied by FT-IR, Polarized FT-NIR, Resonance Raman and UV-Vis Spectroscopy, Recommanded Product: N-Benzyl-2-methyl-4-nitroaniline, the publication is Journal of Physical Chemistry A (2012), 116(7), 1730-1745, database is CAplus and MEDLINE.
FTIR and Raman spectra of the orthorhombic and monoclinic N-benzyl-2-methyl-4-nitroaniline (BNA) single crystals, powders, and BNA solutions were measured in the 15-4000 cm-1 range, and complete assignments of bands to normal vibrations are proposed. The assignments were reinforced by d. functional theory (DFT) calculations Polarized FT-NIR spectra of the orthorhombic (010) BNA plate were measured for the overtones and combinations anal. and for the mech. and elec. anharmonicity estimation Resonance Raman spectra of the orthorhombic BNA polymorph together with the resonance excitation profiles of fundamental and lattice vibrations, compared with the band maxima in the measured UV-visible-NIR spectra of BNA, revealed vibronic couplings with intramol. and intermol. charge transfers. The role of anharmonicity, vibronic couplings and intermol. H bonds and of the N-benzyl substituent are discussed and the origin of 2nd harmonic generation in the orthorhombic BNA crystal is proposed.
Journal of Physical Chemistry A published new progress about 201157-13-3. 201157-13-3 belongs to catalysis-chemistry, auxiliary class Nitro Compound,Amine,Benzene, name is N-Benzyl-2-methyl-4-nitroaniline, and the molecular formula is C14H14N2O2, Recommanded Product: N-Benzyl-2-methyl-4-nitroaniline.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia